Hi Paul:
Diagnosis, of course, is paramount to identifying the cause of this tree's browning foliage. Spraying a tree arbitrarily to cure something unknown is like asking your physician over the phone to prescribe you prescription meds without being properly diagnosed.
Therefore, I would strongly encourage you to contact a certified arborist for an on-site assessment of this tree:
http://illinoisarborist.org/services-we-provide/find-an-arborist/
Best of luck!